Electrochemical Aziridination of Tetrasubstituted Alkenes with Ammonia
نویسندگان
چکیده
منابع مشابه
Synthesis of tetrasubstituted alkenes via metathesis.
Fully substituted olefin generation via metathesis is presented. Catalyst development, optimization of reaction conditions and substrate screening are included. In addition, asymmetric alkene metathesis, the cross metathesis reaction for this transformation and its application in natural products will be discussed.
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[reaction: see text] Reaction of various N-enoyl oxazolidinones 5a-f with N-aminophthalimide and lead tetraacetate in the presence of camphor-derived chiral ligands provides the desired N-phthalimidoaziridines 6a-f in good to high enantiomeric excess (67-95% ee) at 0 degrees C within 15 min. The absolute stereochemistry of the corresponding aziridine derivatives was established by chemical corr...
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ژورنال
عنوان ژورنال: CCS Chemistry
سال: 2021
ISSN: 2096-5745
DOI: 10.31635/ccschem.021.202100826